Ethyldiphenylphosphine
Product Information
Molecular Formula
C14H15P
Molecular Weight
214.24
Description
Catalyst for: Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide; Regio- and stereoselective hydroalkynylation of methylenecyclopropanes; Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles; Dimer to monomer conversion; Tandem Morita-Baylis-Hillman/Michael addition reactions; Platinum-catalyzed cyclization; Regioselective and stereoselective [3+2] cycloaddition; Platinum-catalyzed intermolecular hydroamination; Hydroformylation reactions.
Synonyms
ethyl(diphenyl)phosphine; ethyl(diphenyl)phosphane
IUPAC Name
ethyl(diphenyl)phosphane
SMILES
CCP(C1=CC=CC=C1)C2=CC=CC=C2
InChI
InChI=1S/C14H15P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3
InChI Key
WUOIAOOSKMHJOV-UHFFFAOYSA-N
Boiling Point
293 °C (lit.)
Flash Point
230.0 °F - closed cup
Purity
98 %
Density
1.048 g/mL at 25 °C (lit.)
Refractive Index
n20/D 1.614 (lit.)
LogP
3.13920
Safety Information
Hazards
H302 - H315 - H319 - H335
Precautionary Statement
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
3.4
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
3
Exact Mass
214.091137476 g/mol
Monoisotopic Mass
214.091137476 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
15
Formal Charge
0
Complexity
148
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114105817-A | Method for continuously preparing adiponitrile by hydrocyanating 1, 3-butadiene | 2021-12-10 |
| CN-113582936-A | Synthesis method of palladium-catalyzed N-aryl benzotriazole derivative | 2021-08-11 |
| CN-113461539-A | Method for preparing organic diamine from amino nitrile organic matter | 2021-08-02 |
| CN-113441166-A | Nitrogen-phosphorus co-doped carbon-based cobalt catalyst, preparation method thereof and synthesis method of saturated aliphatic primary amine | 2021-08-02 |
| CN-113385205-A | Metal phosphide catalyst for heterogeneous hydroformylation reaction | 2021-07-16 |
| CN-113214119-A | Selective addition method of dienamine and phenylboronic acid controlled by small steric hindrance | 2021-03-22 |
| JP-2021080483-A | Complex | 2021-03-04 |
| CN-112939917-A | Preparation method of flavonoid compound | 2021-02-08 |
| CN-112387280-A | Method for preparing isopentenal by oxidizing enol | 2020-11-26 |
| CN-112321557-A | Preparation method of Jiale musk | 2020-09-14 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22446986 | 2012-03-02 | Tandem three-component reactions of aldehyde, alkyl acrylate, and dialkylmalonate catalyzed by ethyl diphenylphosphine | Molecules (Basel, Switzerland) |
| 21522535 | 2010-12-24 | Azido-[1,2-bis-(diphenyl-phosphan-yl)ethane-κP,P'](η-inden-yl)ruthenium(II) | Acta crystallographica. Section E, Structure reports online |
| 20976326 | 2010-12-14 | Dinuclear platinum(II) 4,6-diphenyl-2,2'-bipyridine complexes tethered by a rigid bridging ligand: synthesis and photophysics in solution and in LB film | Dalton transactions (Cambridge, England : 2003) |
| 20836513 | 2010-10-18 | Facile determination of the spectra of unstable electrode products using simultaneous fiber-optic chronoabsorptometry and chronoamperometry | Inorganic chemistry |
| 21587711 | 2010-06-16 | Trichloridobis(ethyl-diphenyl-phosphine)(tetra-hydro-furan)-molybdenum(III) | Acta crystallographica. Section E, Structure reports online |
| 21202265 | 2008-04-30 | Chlorido(ethyl-diphenyl-phosphine-κP)(1-pyrrolidinecarbodithio-ato-κS,S')nickel(II) | Acta crystallographica. Section E, Structure reports online |
| 18190207 | 2008-01-07 | Scanning tunneling microscopy studies of pulse deposition of dinuclear organometallic molecules on Au(111) | The Journal of chemical physics |
| 17304612 | 2007-01-01 | Comparative experimental and EXAFS studies in the Mizoroki-Heck reaction with heteroatom-functionalised N-heterocyclic carbene palladium catalysts | Chemistry (Weinheim an der Bergstrasse, Germany) |
| 16129706 | 2005-09-05 | Type I interferons act directly on CD8 T cells to allow clonal expansion and memory formation in response to viral infection | The Journal of experimental medicine |
| 16161315 | 2005-01-01 | [Regulation of glycemia, just where and when in the aged?] | Journees annuelles de diabetologie de l'Hotel-Dieu |
