GPhos Pd G3

Name: GPhos Pd G3
Brand: BOC Sciences
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Molecular Formula:

C48H66NO5PPdS

Molecular Weight:

906.50

CAS Number:

2489525-82-6

Catalog Number:

BPM-501296

Product Information

Molecular Formula

C48H66NO5PPdS

Molecular Weight

906.50

Description

GPhos Pd G3 is a well-defined Buchwald third-generation palladacycle precatalyst featuring a GPhos ligand and a 2'-amino-1,1'-biphenyl-2-yl palladacycle core with a methanesulfonate counterion. It is a powerful precatalyst for classic cross-coupling reactions such as Suzuki-Miyaura, Buchwald-Hartwig amination, and C-N bond formation. The compound is bench-stable and soluble in most organic solvents. This precatalyst offers excellent functional group tolerance and high catalytic activity, making it a valuable tool in pharmaceutical synthesis and organic chemistry research.

Synonyms

Methanesulfonato[Dicyclohexyl[3-(1,1-dimethylethoxy)-6-methoxy-2',6'-bis(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](2'-amino-1,1'-biphenyl-2-yl)palladium(II); Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3-(1,1-dimethylethoxy)-6-methoxy-2',6'-bis(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)-; GPhos Pd G3 Chem Beads; Methanesulfonicacid[2-(dicyclohexylphosphino)-3-tert-butoxy-6-methoxy-2',6'-diisopropyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)

IUPAC Name

dicyclohexyl-[2-[2,6-di(propan-2-yl)phenyl]-3-methoxy-6-[(2-methylpropan-2-yl)oxy]phenyl]phosphane;methanesulfonate;palladium(2+);2-phenylaniline

SMILES

CC(C)C1=C(C(=CC=C1)C(C)C)C2=C(C=CC(=C2P(C3CCCCC3)C4CCCCC4)OC(C)(C)C)OC.CS(=O)(=O)[O-].C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd+2]

InChI

InChI=1S/C35H53O2P.C12H10N.CH4O3S.Pd/c1-24(2)28-20-15-21-29(25(3)4)32(28)33-30(36-8)22-23-31(37-35(5,6)7)34(33)38(26-16-11-9-12-17-26)27-18-13-10-14-19-27;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15,20-27H,9-14,16-19H2,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;;+2/p-1

InChI Key

PLMOFCQYSAAMKA-UHFFFAOYSA-M

Melting Point

>300 °C

Purity

98%

Appearance

Light yellow powder

Storage

Store at 2-8 °C

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GPhos Pd G3

Product Information

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