Methanesulfonato[1,1'-bis(diphenylphosphino)ferrocene)](2'-amino-1,1'-biphenyl-2-yl)palladium(II)

C47H41FeNO3P2PdS

924.11

Methanesulfonato[1,1'-bis(diphenylphosphino)ferrocene)](2'-amino-1,1'-biphenyl-2-yl)palladium(II) is a well-defined Buchwald third-generation palladacycle precatalyst featuring a 1,1'-bis(diphenylphosphino)ferrocene (dppf) ligand and a 2'-amino-1,1'-biphenyl-2-yl palladacycle core with a methanesulfonate counterion. It is a powerful precatalyst for classic cross-coupling reactions such as Suzuki-Miyaura, Buchwald-Hartwig amination, and C-N bond formation. The compound is bench-stable and soluble in most organic solvents. This precatalyst offers excellent functional group tolerance and high catalytic activity, making it a valuable tool in pharmaceutical synthesis and organic chemistry research.

DPPF Pd G3; DPPF Palladacycle Gen. 3; Methanesulfonato[1,1''-bis(diphenylphosphino)ferrocene)](2''-amino-1,1''-biphenyl-2-yl)palladium(II); Methanesulfonato 1,1-ferrocenediyl-bis(diphenylphosphino)(2'-amino-1,1'-biphenyl-2-yl)palladium(II); Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][1-(diphenylphosphino-κP)-1'-(diphenylphosphino)ferrocene](methanesulfonato-κO)-; [2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][1-(diphenylphosphino-κP)-1'-(diphenylphosphino)ferrocene](methanesulfonato-κO)palladium

bis(cyclopenta-1,3-dien-1-yl(diphenyl)phosphane);iron(2+);methanesulfonate;palladium(2+);2-phenylaniline

CS(=O)(=O)[O-].[CH-]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3.[CH-]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Fe+2].[Pd+2]

InChI=1S/2C17H14P.C12H10N.CH4O3S.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*1-14H;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q3*-1;;2*+2/p-1

MTCKUJKQLXVHGO-UHFFFAOYSA-M

134-208 °C

98%

Tawny crystalline powder

Store at 2-8 °C, protect from light, under nitrogen