Diglyme Nickel(II) dibromide
Product Information
Molecular Formula
C6H14Br2NiO3
Molecular Weight
352.67
Description
A nickel salt complex used in catalysis and organic synthesis. Offers stability and solubility in ether solvents.
Synonyms
Nickel, dibromo[1,1'-(oxy-κO)bis[2-(methoxy-κO)ethane]]-; Dibromo[1,1'-(oxy-κO)bis[2-(methoxy-κO)ethane]]nickel; (2-Methoxyethyl ether)]nickel(II) bromide; Diglyme nickel dibromide; 1-Methoxy-2-(2-methoxyethoxy)ethane dibromonickel (1:1); Nickel(II) bromide 2-methoxyethyl ether complex
IUPAC Name
dibromonickel1-methoxy-2-(2-methoxyethoxy)ethane
SMILES
[Br-][Ni+2]12([Br-])O(C)CCO2CCO1C
InChI
InChI=1S/C6H14O3.2BrH.Ni/c1-7-3-5-9-6-4-8-2;;;/h3-6H2,1-2H3;2*1H;/q;;;+2/p-2
InChI Key
RRSIMIHTHWYRRA-UHFFFAOYSA-L
Flash Point
Not applicable
Purity
≥95%
Appearance
Light Yellow to Yellow to Orange Powder to Crystal
Application
Transition Metal Catalysts
Storage
Store at RT under inert atmosphere
Related CAS
733810-17-8 (Deleted CAS) 1033193-29-1 (Deleted CAS)
Safety Information
Hazards
H228 - H302 + H312 + H332 - H315 - H319 - H335
Precautionary Statement
P210 - P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
6
Exact Mass
351.86426 g/mol
Monoisotopic Mass
349.86631 g/mol
Topological Polar Surface Area
27.7Ų
Heavy Atom Count
12
Formal Charge
0
Complexity
44.3
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
2
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114032567-A | Electrochemical reduction carboxylation method based on non-sacrificial anode strategy | 2021-11-23 |
| CN-113754689-A | Nickel-catalyzed asymmetric hydroamination method for olefin | 2021-08-03 |
| CN-112939750-A | Method for transferring asymmetric functionalization by nickel-hydrogen catalysis olefin promoted by ligand relay strategy | 2021-02-04 |
| CN-112679290-A | Nickel-catalyzed asymmetric hydrogen alkynylation method for olefins and application of nickel-catalyzed asymmetric hydrogen alkynylation method in preparation of AMG837 | 2021-01-04 |
| CN-112679290-B | Nickel-catalyzed asymmetric hydrogen alkynylation method for olefins and application of nickel-catalyzed asymmetric hydrogen alkynylation method in preparation of AMG837 | 2021-01-04 |
| CN-113563224-A | Synthesis method of tri-substituted olefin containing gamma-cyano | 2020-12-31 |
| CN-112608208-A | Synthetic method for preparing gamma-cyanoolefin by decarboxylation at room temperature | 2020-12-25 |
| CN-111777571-A | Synthesis method of chiral 2-amino-3- (1, 3-benzothiazole-2-yl) propionic acid hydrochloride | 2020-06-28 |
| CN-112778127-A | Preparation method of flurbiprofen | 2020-06-25 |
| CN-111518125-A | Organosilane synthesis method based on alkenyl chlorosilane coupling reaction | 2020-05-27 |
