Palladium(II) trifluoroacetate
Product Information
Molecular Formula
Pd(O2CCF3)2
Molecular Weight
332.45
Description
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Catalyst used for the mild decarboxylation of electron-rich aromatic acids and the direct cross-coupling of unactivated arenes.
Catalyzes the selective allylic oxidation of geranylacetone and other olefins to their allyl acetates, which can then be converted to keto alcohols.
Catalyst used for the mild decarboxylation of electron-rich aromatic acids and the direct cross-coupling of unactivated arenes.
Catalyzes the selective allylic oxidation of geranylacetone and other olefins to their allyl acetates, which can then be converted to keto alcohols.
Synonyms
PALLADIUM TRIFLUOROACETATE; PALLADIUM(II) TRIFLUOROACETATE; TRIFLUOROACETIC ACID PALLADIUM(II) SALT; 2,7-DICHLORO-9-FLUORENONE, TECH., 90%; PALLADIUM (II) TRIFLUOROACETATE 97+%; Palladium(II) trifluoroacetate, 99+%
IUPAC Name
palladium(2+)2,2,2-trifluoroacetate
SMILES
C(=O)(C(F)(F)F)[O-].C(=O)(C(F)(F)F)[O-].[Pd+2]
InChI
InChI=1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
InChI Key
PBDBXAQKXCXZCJ-UHFFFAOYSA-L
Boiling Point
72.2°Cat 760 mmHg
Melting Point
-220°C
Flash Point
Not applicable
Purity
>98.0%(T)
Appearance
Tan to dark brown powder or crystals
Safety Information
Hazards
H315 - H319 - H335
Precautionary Statement
P302 + P352 - P305 + P351 + P338
Signal Word
Warning
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
10
Rotatable Bond Count
0
Exact Mass
331.87356 g/mol
Monoisotopic Mass
331.87356 g/mol
Topological Polar Surface Area
80.3Ų
Heavy Atom Count
15
Formal Charge
0
Complexity
77.9
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
3
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| KR-20220003875-A | Composition for removing palladium compound and method for removing palladium compound | 2020-07-02 |
| WO-2021191359-A1 | Monoacylglycerol lipase modulators | 2020-03-26 |
| CN-1216091-C | Binitrogen ligand chelated palladium catalyst system and preparation method and application | 2003-01-17 |
| US-4598160-A | Intermediate phenolic compounds for the catalytic synthesis of chromans | 1983-07-15 |
