Poly(maleic anhydride)

Product Information

Molecular Formula:
(C4H2O3)x
Molecular Weight:
0
Description
Polymer reacts with amines. alcohols.
Synonyms
MALEIC ANHYDRIDE POLYMER; POLY(MALEIC ANHYDRIDE); 2,5-Furandione,homopolymer; maleicacidanhydridehomopolymer; maleicanhydride,polymers; maleicanhydridehomopolymer; maleicanhydrideoligomer; poly(maleicacidanhydride)
IUPAC Name
furan-2,5-dione
Canonical SMILES
C1=CC(=O)OC1=O
InChI
InChI=1S/C4H2O3/c5-3-1-2-4(6)7-3/h1-2H
InChI Key
FPYJFEHAWHCUMM-UHFFFAOYSA-N
Boiling Point
202ºC at 760mmHg
Melting Point
52.8ºC
Flash Point
218 °F
Purity
95%
Density
1.484g/cm3
Solubility
Soluble
Appearance
Orthorhombic needles from chloroform
Application
Used in Diel-Alder syntheses; copolymerization reactions; and manufacturing of alkyd-type resins, dye intermediates, pharmaceuticals, and pesticides (Malathion). Other uses are coatings, epoxies, and paper sizing resins.
Storage
Store at room temperature
Stability
Stable under normal laboratory storage conditions.
LogP
log Kow = 1.62
Vapor Pressure
0.2 mmHg
Henry's Law Constant
3.9X10-6 atm-cu m/mol at 25 °C (est)
Decomposition
Maleic anhydride decomposes exothermically, evolving carbon dioxide in the presence of dimethylamine, triethylamine, pyridine, or quinoline at temperatures above 150 °C.
Odor
Pungent odor

Safety Information

Hazards
Unknown
Handling
Gloves & fume hood

Computed Properties

XLogP3
-0.1
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
0
Exact Mass
98.000393922 g/mol
Monoisotopic Mass
98.000393922 g/mol
Topological Polar Surface Area
43.4Ų
Heavy Atom Count
7
Formal Charge
0
Complexity
129
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
US-2015337147-A1 Reversible polymers in 3-d printing 2014-05-22
US-2015329525-A1 Pyrrolidine-2, 5-dione derivatives, pharmaceutical compositions and methods for use as ido1 inhibitors 2014-05-15
US-2016200730-A1 Polyfluorinated compounds acting as bruton tyrosine kinase inhibitors 2014-04-29
US-2015240084-A1 Composition and method for use in three dimensional printing 2014-02-25
US-2016200960-A1 Compositions and methods for forming and utilizing stable, single-component resin mixture 2013-09-20
US-2016222024-A1 S-enantiomer of tetracyclic indole derivative as pbr ligands 2013-09-20
US-2015060831-A1 Surface-modified organic semiconductors 2013-09-05
US-2016207865-A1 Process for manufacturing acrylic acid, acrylonitrile and 1,4-butanediol from 1,3-propanediol 2013-09-03
US-2016200666-A1 Cyclic vinylogous amides as bromodomain inhibitors 2013-08-30
US-2016200902-A1 Rubber composition and tire 2013-08-23

Literatures

PMID Publication Date Title Journal
29540657 2018-01-01 Improvement of human cell line activation test (h-CLAT) using short-time exposure methods for prevention of false-negative results The Journal of toxicological sciences
26795242 2016-04-01 SENS-IS, a 3D reconstituted epidermis based model for quantifying chemical sensitization potency: Reproducibility and predictivity results from an inter-laboratory study Toxicology in vitro : an international journal published in association with BIBRA
24211530 2014-03-01 Gene expressions changes in bronchial epithelial cells: markers for respiratory sensitizers and exploration of the NRF2 pathway Toxicology in vitro : an international journal published in association with BIBRA
22941771 2012-12-01 Synthesis, characterization, and biocompatibility of a novel biomimetic material based on MGF-Ct24E modified poly(D, L-lactic acid) Journal of biomedical materials research. Part A
22621748 2012-11-01 Ultrasound assisted copolymerization of acrylonitrile with N-amino phenyl maleimides and N-amino phenyl 2,3 dimethyl maleimides Ultrasonics sonochemistry
22847991 2012-10-01 Selective conversion of furfural to maleic anhydride and furan with VO(x)/Al(2)O(3) catalysts ChemSusChem
22889067 2012-09-26 Improved electrical conductivity of polyamide 12/graphene nanocomposites with maleated polyethylene-octene rubber prepared by melt compounding ACS applied materials & interfaces
22855404 2012-08-27 Morphology- and phase-controlled iron oxide nanoparticles stabilized with maleic anhydride grafted polypropylene Angewandte Chemie (International ed. in English)
22867432 2012-08-22 Unconventional titania photocatalysis: direct deployment of carboxylic acids in alkylations and annulations Journal of the American Chemical Society
22796348 2012-08-15 Bioengineering functional copolymers. XXI. Synthesis of a novel end carboxyl-trithiocarbonate functionalized poly(maleic anhydride) and its interaction with cancer cells Bioorganic & medicinal chemistry
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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