Poly(maleic anhydride)
Product Information
Molecular Formula
(C4H2O3)x
Description
Polymer reacts with amines. alcohols.
Synonyms
MALEIC ANHYDRIDE POLYMER; POLY(MALEIC ANHYDRIDE); 2,5-Furandione,homopolymer; maleicacidanhydridehomopolymer; maleicanhydride,polymers; maleicanhydridehomopolymer; maleicanhydrideoligomer; poly(maleicacidanhydride)
IUPAC Name
furan-2,5-dione
SMILES
C1=CC(=O)OC1=O
InChI
InChI=1S/C4H2O3/c5-3-1-2-4(6)7-3/h1-2H
InChI Key
FPYJFEHAWHCUMM-UHFFFAOYSA-N
Boiling Point
202°C at 760mmHg
Melting Point
52.8°C
Flash Point
218 °F
Purity
95%
Density
1.484g/cm3
Solubility
Soluble
Appearance
Orthorhombic needles from chloroform
Application
Used in Diel-Alder syntheses; copolymerization reactions; and manufacturing of alkyd-type resins, dye intermediates, pharmaceuticals, and pesticides (Malathion). Other uses are coatings, epoxies, and paper sizing resins.
Storage
Store at room temperature
Stability
Stable under normal laboratory storage conditions.
LogP
log Kow = 1.62
Vapor Pressure
0.2 mmHg
Henry's Law Constant
3.9X10-6 atm-cu m/mol at 25 °C (est)
Decomposition
Maleic anhydride decomposes exothermically, evolving carbon dioxide in the presence of dimethylamine, triethylamine, pyridine, or quinoline at temperatures above 150 °C.
Odor
Pungent odor
Safety Information
Hazards
Unknown
Handling
Gloves & fume hood
Computed Properties
XLogP3
-0.1
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
0
Exact Mass
98.000393922 g/mol
Monoisotopic Mass
98.000393922 g/mol
Topological Polar Surface Area
43.4Ų
Heavy Atom Count
7
Formal Charge
0
Complexity
129
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| US-2015337147-A1 | Reversible polymers in 3-d printing | 2014-05-22 |
| US-2015329525-A1 | Pyrrolidine-2, 5-dione derivatives, pharmaceutical compositions and methods for use as ido1 inhibitors | 2014-05-15 |
| US-2016200730-A1 | Polyfluorinated compounds acting as bruton tyrosine kinase inhibitors | 2014-04-29 |
| US-2015240084-A1 | Composition and method for use in three dimensional printing | 2014-02-25 |
| US-2016200960-A1 | Compositions and methods for forming and utilizing stable, single-component resin mixture | 2013-09-20 |
| US-2016222024-A1 | S-enantiomer of tetracyclic indole derivative as pbr ligands | 2013-09-20 |
| US-2015060831-A1 | Surface-modified organic semiconductors | 2013-09-05 |
| US-2016207865-A1 | Process for manufacturing acrylic acid, acrylonitrile and 1,4-butanediol from 1,3-propanediol | 2013-09-03 |
| US-2016200666-A1 | Cyclic vinylogous amides as bromodomain inhibitors | 2013-08-30 |
| US-2016200902-A1 | Rubber composition and tire | 2013-08-23 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 29540657 | 2018-01-01 | Improvement of human cell line activation test (h-CLAT) using short-time exposure methods for prevention of false-negative results | The Journal of toxicological sciences |
| 26795242 | 2016-04-01 | SENS-IS, a 3D reconstituted epidermis based model for quantifying chemical sensitization potency: Reproducibility and predictivity results from an inter-laboratory study | Toxicology in vitro : an international journal published in association with BIBRA |
| 24211530 | 2014-03-01 | Gene expressions changes in bronchial epithelial cells: markers for respiratory sensitizers and exploration of the NRF2 pathway | Toxicology in vitro : an international journal published in association with BIBRA |
| 22941771 | 2012-12-01 | Synthesis, characterization, and biocompatibility of a novel biomimetic material based on MGF-Ct24E modified poly(D, L-lactic acid) | Journal of biomedical materials research. Part A |
| 22621748 | 2012-11-01 | Ultrasound assisted copolymerization of acrylonitrile with N-amino phenyl maleimides and N-amino phenyl 2,3 dimethyl maleimides | Ultrasonics sonochemistry |
| 22847991 | 2012-10-01 | Selective conversion of furfural to maleic anhydride and furan with VO(x)/Al(2)O(3) catalysts | ChemSusChem |
| 22889067 | 2012-09-26 | Improved electrical conductivity of polyamide 12/graphene nanocomposites with maleated polyethylene-octene rubber prepared by melt compounding | ACS applied materials & interfaces |
| 22855404 | 2012-08-27 | Morphology- and phase-controlled iron oxide nanoparticles stabilized with maleic anhydride grafted polypropylene | Angewandte Chemie (International ed. in English) |
| 22867432 | 2012-08-22 | Unconventional titania photocatalysis: direct deployment of carboxylic acids in alkylations and annulations | Journal of the American Chemical Society |
| 22796348 | 2012-08-15 | Bioengineering functional copolymers. XXI. Synthesis of a novel end carboxyl-trithiocarbonate functionalized poly(maleic anhydride) and its interaction with cancer cells | Bioorganic & medicinal chemistry |
