TETRAHYDROXYDIBORON

Product Information

Molecular Formula:
B2H4O4
Molecular Weight:
89.65
Description
Tetrahydroxydiboron (BBA) is an efficient borylating agent that can be used to borylate a wide variety of aryl and heteroaryl substrates with low Pd- and Ni-catalyst loads.Other reactions employing BBA as a reagent:• Palladium-catalyzed boronation of vinyl cyclopropane, vinyl aziridine, and allyl acetate substrates.• To facilitate catalytic transfer hydrogenations of simple alkenes and alkynes.• Selective reducing agent for in situ N-oxide reduction of pyridine-N-oxides.• As a substitute to bis(pinacolato) diboron for Miyaura borylation.
Synonyms
TETRAHYDROXYDIBORON; Hypoboric acid; sub-Boric acid
IUPAC Name
hypoboric acid
Canonical SMILES
B(B(O)O)(O)O
InChI
InChI=1S/B2H4O4/c3-1(4)2(5)6/h3-6H
InChI Key
SKOWZLGOFVSKLB-UHFFFAOYSA-N
Melting Point
>385 °C
Flash Point
Not applicable
Purity
N/A

Safety Information

Hazards
H302 + H332 - H315 - H319 - H335
Precautionary Statement
P301 + P312 + P330 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338

Computed Properties

Hydrogen Bond Donor Count
4
Hydrogen Bond Acceptor Count
4
Rotatable Bond Count
1
Exact Mass
90.0295689 g/mol
Monoisotopic Mass
90.0295689 g/mol
Topological Polar Surface Area
80.9Ų
Heavy Atom Count
6
Formal Charge
0
Complexity
26.5
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
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CN-113666946-A Preparation method of 2 beta-triazole methyl penicillanic acid diphenylmethyl ester, tazobactam intermediate and tazobactam 2021-10-25
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CN-114023950-A Surface-stable amorphous passivation layer coated lithium ion battery positive electrode material and preparation method thereof 2021-09-30
CN-113816925-A A trematopsin 3 "-tert-butyl-4 '- (2-hydroxyethoxy) -4" -pyrrolidin-1-yl [1, 1'; process for preparing 3 ', 1' ] -terphenyl-4-carboxylic acid 2021-09-18
CN-113354675-A Preparation method of 4-hydroxymethyl phenylboronic acid 2021-07-01
CN-112724167-A Preparation method of clitorium 2021-01-13
CN-112607831-A Active element uniformly-doped thin film electrode and preparation method thereof 2020-12-17
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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