Tri(2-furyl)phosphine
Product Information
Molecular Formula
C12H9O3P
Molecular Weight
232.17
Description
Tri(2-furyl)phosphine (CAS# 5518-52-5) is a useful research chemical.
Synonyms
tris(2-furanyl)phosphine; tris(furan-2-yl)phosphane
IUPAC Name
tris(furan-2-yl)phosphane
SMILES
C1=COC(=C1)P(C2=CC=CO2)C3=CC=CO3
InChI
InChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
InChI Key
DLQYXUGCCKQSRJ-UHFFFAOYSA-N
Boiling Point
136 °C / 4 mmHg (lit.)
Melting Point
59-64 °C (lit.)
Flash Point
Not applicable
Purity
99 %
LogP
2.22380
Safety Information
Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
2.8
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
3
Exact Mass
232.02893114 g/mol
Monoisotopic Mass
232.02893114 g/mol
Topological Polar Surface Area
39.4Ų
Heavy Atom Count
16
Formal Charge
0
Complexity
198
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114015021-A | Terminal functional side chain substituted pyrrolopyrroledione-based terpolymer and preparation method and application thereof | 2021-10-28 |
| CN-113817157-A | Semi-aromatic polyamide polycondensation catalyst and preparation method thereof | 2021-09-28 |
| CN-113831272-A | Method for synthesizing 2-substituted indole compound by using palladium to catalyze iodobenzene and oxime ester | 2021-09-26 |
| CN-113773294-A | Preparation method and application of flavone and isoflavone compounds | 2021-09-18 |
| CN-113683551-A | N-tert-butyl-2-phenylindole derivative, preparation method and application | 2021-09-09 |
| CN-113224313-A | Metal organic phosphine frame glass modified metal negative current collector and preparation method thereof | 2021-04-30 |
| CN-113087691-A | Method for synthesizing chiral aryl tertiary alcohol and benzopyran compound based on kinetic resolution strategy | 2021-03-26 |
| CN-113372184-A | Method for synthesizing C-N axis chiral phenanthridinone compound based on chiral transfer strategy | 2021-03-26 |
| CN-113061234-A | Benzothiadiazole polymer, electron transport compound and perovskite photoelectric element | 2021-03-22 |
| CN-113061235-A | Copolymer and organic photovoltaic element | 2021-03-22 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22740322 | 2012-07-27 | One-pot approach to installing eight-membered rings onto indoles | Angewandte Chemie (International ed. in English) |
| 19317401 | 2009-04-15 | Enhancement of a catalysis-based fluorometric detection method for palladium through rational fine-tuning of the palladium species | Journal of the American Chemical Society |
| 18759388 | 2008-09-24 | Branch-selective reductive coupling of 2-vinyl pyridines and imines via rhodium catalyzed C-C bond forming hydrogenation | Journal of the American Chemical Society |
| 17107096 | 2006-11-23 | Reductive aldol coupling of divinyl ketones via rhodium-catalyzed hydrogenation: syn-diastereoselective construction of beta-hydroxyenones | Organic letters |
| 16435874 | 2006-02-02 | Hydrogen-mediated aldol reductive coupling of vinyl ketones catalyzed by rhodium: high syn-selectivity through the effect of tri-2-furylphosphine | Organic letters |
| 15252611 | 2004-05-21 | Unsuccessful/successful attempts to produce penta(heteroaryl)-phosphoranes/-arsoranes R5E (E = P, As; R = 2-furyl, 2-thienyl) | Dalton transactions (Cambridge, England : 2003) |
| 14664564 | 2003-12-17 | Palladium-catalyzed Stille cross-couplings of sulfonyl chlorides and organostannanes | Journal of the American Chemical Society |
| 12772895 | 2003-05-07 | Palladium catalysed cyclisation-carbonylation of enynes to give cyclic gamma,delta-unsaturated acids | Chemical communications (Cambridge, England) |
| 12375972 | 2002-10-18 | Palladium-catalyzed selective synthesis of 2-allyltetrazoles | The Journal of organic chemistry |
| 12358538 | 2002-10-09 | Synthesis of allyl cyanamides and N-cyanoindoles via the palladium-catalyzed three-component coupling reaction | Journal of the American Chemical Society |
