Tributyl(1-ethoxyvinyl)stannane
Product Information
Molecular Formula
C16H34OSn
Molecular Weight
361.15
Description
Electrophilic methyl ketone equivalent used in a recent synthesis of a 13-oxophorbine (chlorophyll) from the corresponding 13-bromochlorin.
Reagent employed in palladium-catalyzed coupling reactions with sulfoxides, α-haloethers, and chlorocyclobutenones. Also used to convert acid chlorides to α-oxygenated enones.
Reagent employed in palladium-catalyzed coupling reactions with sulfoxides, α-haloethers, and chlorocyclobutenones. Also used to convert acid chlorides to α-oxygenated enones.
Synonyms
Tributyl(1-ethoxyvinyl)tin; tributyl(1-ethoxyethenyl)stannane; 1-ethoxyvinyltri-n-butyltin; 1-Ethoxyvinyltributyltin; Stannane, tributyl(1-ethoxyethenyl)-; (1-ethoxyvinyl)tributyltin; (1-Ethoxyvinyl)tributylstannane; (1-Ethoxyethenyl)tributylstannane; TRIBUTYL-(1-ETHOXYVINYL)TIN; EVTB; (1ethoxyvinyl)tributyltin; 1-ethoxy-vinyltributyltin; tributyl(1ethoxyvinyl)tin; tributyl-1-ethoxyvinyltin; tributyl(l ethoxyvinyl)tin; tributyl(l-ethoxyvinyl)tin; tributyl(I-ethoxyvinyl)tin; 1-ethoxyvinyl tributyl tin; tributyl(1 ethoxyvinyl)tin; l-ethoxyvinyltributylstannane; tributyl-(l-ethoxyvinyl)tin; (1-ethoxyvinyl)-tributyltin; 1-ethoxyvinyltributylstannane; tri-butyl(1-ethoxyvinyl)tin; tributyl (1-ethoxyvinyl)tin; tributyl(1-ethoxy vinyl)tin; tributyl(1-ethoxy-vinyl)tin; tributyl(1-ethoxyvinyl) tin; (1-Ethoxyvinyl)tributyl tin
IUPAC Name
tributyl(1-ethoxyethenyl)stannane
SMILES
CCCC[Sn](CCCC)(CCCC)C(=C)OCC
InChI
InChI=1S/C4H7O.3C4H9.Sn/c1-3-5-4-23*1-3-4-2/h1,4H2,2H33*1,3-4H2,2H3
InChI Key
HGXJOXHYPGNVNK-UHFFFAOYSA-N
Boiling Point
85-86 °C/0.1 mmHg (lit.)
Flash Point
235.4 °F - closed cup
Purity
95%
Density
1.069 g/mL at 25 °C (lit.)
Refractive Index
n20/D 1.476 (lit.)
Safety Information
Hazards
H301 - H315 - H319 - H372 - H400
Precautionary Statement
P273 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 - P314
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
1
Rotatable Bond Count
12
Exact Mass
362.163168 g/mol
Monoisotopic Mass
362.163168 g/mol
Topological Polar Surface Area
9.2Ų
Heavy Atom Count
18
Formal Charge
0
Complexity
191
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| JP-2022031355-A | Pest control method | 2021-12-15 |
| JP-2021152083-A | Pest control method | 2021-07-02 |
| JP-2021152084-A | Pest control method | 2021-07-02 |
| WO-2022049146-A1 | Pesticidally active heterocyclic derivatives with sulfur containing substituents | 2020-09-02 |
| WO-2022047145-A1 | Rapidly accelerating fibrosarcoma protein degrading compounds and associated methods of use | 2020-08-28 |
| US-2022064165-A1 | Tricyclic urea compounds as jak2 v617f inhibitors | 2020-08-27 |
| WO-2022046989-A1 | Tricyclic urea compounds as jak2 v617f inhibitors | 2020-08-27 |
| WO-2022042630-A1 | Heteroaryl compounds, preparation methods and uses thereof | 2020-08-26 |
| WO-2022037525-A1 | Acetophenone oxime compound and application thereof | 2020-08-20 |
| WO-2022036204-A1 | Compounds, compositions and methods | 2020-08-14 |
