Trimethylolpropane trimethacrylate
Product Information
Molecular Formula
C18H26O6
Molecular Weight
338.40
Description
Crosslinking monomer.
Synonyms
2,2-bis(2-methylprop-2-enoyloxymethyl)butyl 2-methylprop-2-enoate
IUPAC Name
2,2-bis(2-methylprop-2-enoyloxymethyl)butyl 2-methylprop-2-enoate
SMILES
CCC(COC(=O)C(=C)C)(COC(=O)C(=C)C)COC(=O)C(=C)C
InChI
InChI=1S/C18H26O6/c1-8-18(9-22-15(19)12(2)3,10-23-16(20)13(4)5)11-24-17(21)14(6)7/h2,4,6,8-11H2,1,3,5,7H3
InChI Key
OKKRPWIIYQTPQF-UHFFFAOYSA-N
Boiling Point
>200 °C / 1 mmHg
Melting Point
-25 °C
Flash Point
182 °C
Purity
95 %
Density
1.06 g/cm3
Solubility
water, 1.297 mg/L @ 25 °C (est)
Appearance
Colorless to yellow viscous liquid
Application
Trimethylolpropane trimethacrylate is used in the preparation of macroporous poly (glycidyl methacrylate-co-trimethylolpropane trimethacrylate) materials with fine controlled porous properties.
Storage
Store at 4 degrees celsius
Grade
technical grade
Refractive Index
n20/D 1.472
LogP
2.74070
Vapor Pressure
<0.01 mmHg ( 20 °C)
Safety Information
Hazards
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
H413:
May cause long-lasting harmful effects to aquatic life.
Causes skin irritation.
H319:
Causes serious eye irritation.
H413:
May cause long-lasting harmful effects to aquatic life.
Precautionary Statement
P264:
Wash thoroughly after handling.
P273:
Avoid release to the environment.
P280:
Wear protective gloves/protective clothing/eye protection/face protection.
P332+P313:
If skin irritation occurs:
Get medical advice/attention.
P337+P313:
If eye irritation persists:
Get medical advice/attention.
P501:
Dispose of contents/container in accordance with local/regional/national/international regulations.
Wash thoroughly after handling.
P273:
Avoid release to the environment.
P280:
Wear protective gloves/protective clothing/eye protection/face protection.
P332+P313:
If skin irritation occurs:
Get medical advice/attention.
P337+P313:
If eye irritation persists:
Get medical advice/attention.
P501:
Dispose of contents/container in accordance with local/regional/national/international regulations.
Computed Properties
XLogP3
3.8
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
6
Rotatable Bond Count
13
Exact Mass
338.17293854 g/mol
Monoisotopic Mass
338.17293854 g/mol
Topological Polar Surface Area
78.9Ų
Heavy Atom Count
24
Formal Charge
0
Complexity
470
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| EP-3841908-A1 | Cushion and shoe | 2019-12-27 |
| EP-3841909-A1 | Cushion and shoe | 2019-12-27 |
| EP-3842798-A1 | Colorimetric drug test strip using porous support material | 2019-12-23 |
| US-2021187903-A1 | Thermal insulation components and methods of manufacturing thermal insulation components | 2019-12-23 |
| US-2021190697-A1 | Colorimetric drug test strip using porous support material | 2019-12-23 |
| US-2021186822-A1 | Dental material containing nanosized fillers and preparation methods thereof | 2019-12-20 |
| WO-2021124816-A1 | Rubber composition and vulcanized molded product | 2019-12-20 |
| EP-3838936-A1 | Curable compositions comprising multistage polymers | 2019-12-19 |
| US-2021190992-A1 | Contact lens containing photosensitive chromophore and package therefor | 2019-12-19 |
| WO-2021125837-A1 | Hydrogenated petroleum resin and rubber composition comprising same | 2019-12-17 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22996033 | 2012-10-01 | Preparation and characterization of grafted imprinted monolith for capillary electrochromatography | Electrophoresis |
| 22771349 | 2012-09-15 | Non-chromatographic mercury speciation and determination in wine by new core-shell ion-imprinted sorbents | Journal of hazardous materials |
| 22733549 | 2012-07-01 | Synthesis and evaluation of uniformly sized nalidixic acid-imprinted nanospheres based on precipitation polymerization method for analytical and biomedical applications | Journal of molecular recognition : JMR |
| 22534800 | 2012-06-07 | Rational design of molecularly imprinted polymer: the choice of cross-linker | The Analyst |
| 22282199 | 2012-05-02 | Controlled synthesis of bulk polymer nanocomposites with tunable second order nonlinear optical properties | Advanced materials (Deerfield Beach, Fla.) |
| 22217269 | 2012-01-18 | Modification and characterization of biodegradable methylcellulose films with trimethylolpropane trimethacrylate (TMPTMA) by γ radiation: effect of nanocrystalline cellulose | Journal of agricultural and food chemistry |
| 21976449 | 2011-11-01 | Photo-crosslinkable cyanoacrylate bioadhesive: shrinkage kinetics, dynamic mechanical properties, and biocompatibility of adhesives containing TMPTMA and POSS nanostructures as crosslinking agents | Journal of biomedical materials research. Part A |
| 21855075 | 2011-10-07 | Molecularly imprinted polymer grafted to porous polyethylene frits: a new selective solid-phase extraction format | Journal of chromatography. A |
| 21909495 | 2011-10-01 | Microshear bond strength and interfacial morphology of etch-and-rinse and self-etch adhesive systems to superficial and deep dentin | Quintessence international (Berlin, Germany : 1985) |
| 20564693 | 2010-06-01 | pCEC coupling with ESI-MS for the analysis of beta(2)-agonists and narcotics using a poly-(1-hexadecene-co-TMPTMA) monolithic column | Electrophoresis |
