TRIS(2,2,2-TRIFLUOROETHYL) BORATE
Product Information
Molecular Formula
C6H6BF9O3
Molecular Weight
307.91
Description
Reagent can promote the direct formation of amides from carboxylic acids and amines under thermal and microwave conditions.
Synonyms
TRIS(TRIFLUOROETHYL)BORATE; TRIS(2,2,2-TRIFLUOROETHYL) BORATE
IUPAC Name
tris(2,2,2-trifluoroethyl) borate
SMILES
B(OCC(F)(F)F)(OCC(F)(F)F)OCC(F)(F)F
InChI
InChI=1S/C6H6BF9O3/c8-4(9,10)1-17-7(18-2-5(11,12)13)19-3-6(14,15)16/h1-3H2
InChI Key
DIEXQJFSUBBIRP-UHFFFAOYSA-N
Boiling Point
125 °C
Flash Point
109.9 °F
Purity
>95.0%(T)
Density
1.430 g/mL at 25 °C
Appearance
Colorless to Almost colorless clear liquid
Storage
Store under inert gas
Refractive Index
1.3
Safety Information
Hazards
H226
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
12
Rotatable Bond Count
6
Exact Mass
308.0266277 g/mol
Monoisotopic Mass
308.0266277 g/mol
Topological Polar Surface Area
27.7Ų
Heavy Atom Count
19
Formal Charge
0
Complexity
217
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-113717176-A | Method for preparing remazolam | 2021-10-09 |
| CN-113782833-A | Electrolyte and preparation method and application thereof | 2021-09-27 |
| CN-114122515-A | Lithium secondary battery flame-retardant electrolyte based on two-dimensional structure design and application | 2021-09-23 |
| CN-113690484-A | Rechargeable magnesium-sulfur battery electrolyte and preparation method thereof | 2021-08-26 |
| CN-113363578-A | Boron-based non-nucleophilic rechargeable magnesium battery electrolyte and preparation method thereof | 2021-06-08 |
| CN-112786966-A | Electrolyte and lithium ion battery | 2021-03-01 |
| CN-114122259-A | Perovskite thin-film solar cell and preparation method thereof | 2020-08-29 |
| CN-111769326-A | Ternary cathode material lithium ion battery electrolyte | 2020-06-18 |
| CN-111313094-A | High-voltage electrolyte additive for lithium-rich manganese-based lithium ion battery, electrolyte, lithium battery and preparation method of high-voltage electrolyte additive | 2020-05-14 |
| CN-111313094-B | High-voltage electrolyte additive for lithium-rich manganese-based lithium battery and preparation method thereof | 2020-05-14 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 21212879 | 2011-03-07 | Borate esters as convenient reagents for direct amidation of carboxylic acids and transamidation of primary amides | Organic & biomolecular chemistry |
