TRIS(2,4,6-TRIMETHOXYPHENYL)PHOSPHINE
Product Information
Molecular Formula
C27H33O9P
Molecular Weight
532.52
Description
Highly basic arylphosphine.
Synonyms
Phosphine, tris(2,4,6-trimethoxyphenyl)-; TRIS(2,4,6-TRIMETHOXYPHENYL)PHOSPHINE; TTMPP; Tris(2,4,6-trimethoxyphenyl)phosphine,min.97%; Tris(2,4,6-trimethoxyphenyl)phosphine, min. 97%; Tri(2,4,6-trimethoxyphenyl)phosphine
IUPAC Name
tris(2,4,6-trimethoxyphenyl)phosphane
SMILES
COC1=CC(=C(C(=C1)OC)P(C2=C(C=C(C=C2OC)OC)OC)C3=C(C=C(C=C3OC)OC)OC)OC
InChI
InChI=1S/C27H33O9P/c1-28-16-10-19(31-4)25(20(11-16)32-5)37(26-21(33-6)12-17(29-2)13-22(26)34-7)27-23(35-8)14-18(30-3)15-24(27)36-9/h10-15H,1-9H3
InChI Key
JQKHNBQZGUKYPX-UHFFFAOYSA-N
Melting Point
155-160 °C (lit.)
Flash Point
Not applicable
Computed Properties
XLogP3
4.3
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
9
Rotatable Bond Count
12
Exact Mass
532.18621962 g/mol
Monoisotopic Mass
532.18621962 g/mol
Topological Polar Surface Area
83.1Ų
Heavy Atom Count
37
Formal Charge
0
Complexity
530
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-112876658-A | Dithienopyrrole-based polymer and preparation method and application thereof | 2021-03-02 |
| CN-112661939-A | Polymer, preparation method and application thereof | 2020-12-17 |
| CN-111808041-A | Difluoroalkyl aryl oxazolidinone compound and preparation method thereof | 2020-08-17 |
| JP-2022028533-A | Curable resin composition and its use | 2020-08-03 |
| CN-111825715-A | Synthesis method of triphenylphosphine derivative tri- (R-phenyl) phosphine | 2020-07-16 |
| JP-2021183314-A | Emulsifying composition containing emulsifier and emulsifier | 2020-05-22 |
| JP-2021183676-A | Production method of diblock type copolymer, diblock type copolymer and use of diblock type copolymer | 2020-05-22 |
| WO-2021235266-A1 | Diblock copolymer, method for producing diblock copolymer, and use of diblock copolymer | 2020-05-22 |
| WO-2021235274-A1 | Emulsifier and emulsion composition containing same | 2020-05-22 |
| CN-111574707-A | Modified polyphenyl ether, preparation method thereof, ion exchange membrane containing modified polyphenyl ether, preparation method and application | 2020-05-15 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 20550218 | 2010-07-16 | Ru-catalyzed decarbonylative addition of aliphatic aldehydes to terminal alkynes | Organic letters |
| 19707684 | 2009-09-21 | TTMPP: An efficient organocatalyst in the ring-opening of aziridines with silylated nucleophiles | Organic & biomolecular chemistry |
| 19783929 | 2009-09-02 | Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): efficient catalysts for the cyanosilylation and cyanocarbonation of aldehydes and ketones | Molecules (Basel, Switzerland) |
