Tris(o-methoxyphenyl)phosphine
Product Information
Molecular Formula
C21H21O3P
Molecular Weight
352.36
Description
Catalyst for: Allylic substitution of simple alkenes; Suzuki coupling reactions; Telomerization of 1,3-butadiene with various alcohols; Hydrogenation of quinolines; Amination / direct arylation.
Synonyms
tris(2-methoxyphenyl)phosphine; tris(2-methoxyphenyl)phosphane
IUPAC Name
tris(2-methoxyphenyl)phosphane
SMILES
COC1=CC=CC=C1P(C2=CC=CC=C2OC)C3=CC=CC=C3OC
InChI
InChI=1S/C21H21O3P/c1-22-16-10-4-7-13-19(16)25(20-14-8-5-11-17(20)23-2)21-15-9-6-12-18(21)24-3/h4-15H,1-3H3
InChI Key
IIOSDXGZLBPOHD-UHFFFAOYSA-N
Boiling Point
477.3 °C at 760 mmHg
Melting Point
198-204 °C
Flash Point
Not applicable
Purity
96 %
LogP
3.47060
Safety Information
Hazards
H315 - H319 - H335 - H413
Precautionary Statement
P261, P264, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
4.5
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
6
Exact Mass
352.12283153 g/mol
Monoisotopic Mass
352.12283153 g/mol
Topological Polar Surface Area
27.7Ų
Heavy Atom Count
25
Formal Charge
0
Complexity
334
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114181263-A | Monocarborane anion platinum complex-containing blue light material and preparation method and application thereof | 2021-12-20 |
| CN-113979918-A | C-3-position five-membered spiro indolone derivative containing all-carbon tetra-substituted olefin structure and preparation and application thereof | 2021-11-04 |
| CN-113816878-A | Preparation method of 3-butene-1-sulfonyl fluoride compound | 2021-11-02 |
| CN-113881019-A | 2-indolone-based polymer donor material and preparation method thereof | 2021-10-18 |
| CN-113621002-A | Metal organic complex containing monocarborane and nitrogen heterocyclic carbene and preparation method thereof | 2021-09-24 |
| CN-113801310-A | Three-component catalytic initiation system catalyst and application thereof | 2021-09-24 |
| CN-113683646-A | Monocarbon borane-containing metal platinum complex and preparation method and application thereof | 2021-09-18 |
| CN-113754868-A | Conjugated polymer based on thiophene and benzothiadiazole and preparation method thereof | 2021-08-31 |
| CN-113754869-A | Fused ring polymer donor material based on benzothiadiazole or benzoselenadiazole and preparation method thereof | 2021-08-31 |
| CN-113087673-A | Preparation method of alkyl/alkenyl substituted nitrogen-containing heterocyclic compound | 2021-04-07 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 21578098 | 2009-10-10 | trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II) | Acta crystallographica. Section E, Structure reports online |
| 21582816 | 2009-06-06 | Tris(2-methoxy-phen-yl)phosphine | Acta crystallographica. Section E, Structure reports online |
| 19708052 | 2009-01-01 | Base-free Pd/TOMPP-catalyzed telomerization of 1,3-butadiene with carbohydrates and sugar alcohols | ChemSusChem |
| 14551430 | 2003-10-10 | Phosphadioxirane: a peroxide from an ortho-substituted arylphosphine and singlet dioxygen | Science (New York, N.Y.) |
