Tris(pentafluorophenyl)phosphine
Product Information
Molecular Formula
C18F15P
Molecular Weight
532.14
Description
Tris(pentafluorophenyl)phosphine (CAS# 1259-35-4) is a useful research chemical.
Synonyms
tris(2,3,4,5,6-pentafluorophenyl)phosphine; tris(2,3,4,5,6-pentafluorophenyl)phosphane
IUPAC Name
tris(2,3,4,5,6-pentafluorophenyl)phosphane
SMILES
C1(=C(C(=C(C(=C1F)F)P(C2=C(C(=C(C(=C2F)F)F)F)F)C3=C(C(=C(C(=C3F)F)F)F)F)F)F)F
InChI
InChI=1S/C18F15P/c19-1-4(22)10(28)16(11(29)5(1)23)34(17-12(30)6(24)2(20)7(25)13(17)31)18-14(32)8(26)3(21)9(27)15(18)33
InChI Key
FQLSDFNKTNBQLC-UHFFFAOYSA-N
Boiling Point
343.4 °C at 760 mmHg
Melting Point
108-110 °C (lit.)
Flash Point
Not applicable
Purity
97 %
Solubility
Insoluble in water.
Appearance
Cream solid
Storage
Inert atmosphere, Room Temperature
LogP
5.53130
Safety Information
Hazards
H315 - H319 - H335
Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
6.1
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
15
Rotatable Bond Count
3
Exact Mass
531.9498094 g/mol
Monoisotopic Mass
531.9498094 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
34
Formal Charge
0
Complexity
566
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-113937223-A | Preparation method of functional molecule co-doped perovskite solar cell | 2021-12-15 |
| CN-113937223-B | Preparation method of functional molecule co-doped perovskite solar cell | 2021-12-15 |
| CN-113629199-A | Pretreatment method for improving interface passivation effect of perovskite solar cell | 2021-09-02 |
| CN-113506919-A | Lithium supplementing process for pre-mixing powder and electrolyte into film | 2021-07-15 |
| CN-113224313-A | Metal organic phosphine frame glass modified metal negative current collector and preparation method thereof | 2021-04-30 |
| CN-112898247-A | Synthetic method of furan acetate compound | 2021-03-09 |
| CN-112448037-A | Lithium supplementing composition, lithium supplementing electrolyte and lithium supplementing method for lithium secondary battery | 2020-11-30 |
| CN-111799381-A | Preparation method of perovskite solar cell based on phosphorus-containing hole dopant | 2020-09-10 |
| CN-111799381-B | Preparation method of perovskite solar cell based on phosphorus-containing hole dopant | 2020-09-10 |
| CN-111808041-A | Difluoroalkyl aryl oxazolidinone compound and preparation method thereof | 2020-08-17 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 20530825 | 2010-01-01 | Probing bare high-valent transition oxo-metal complexes: an electrospray ionization Fourier transform ion cyclotron resonance study of reactive intermediates | European journal of mass spectrometry (Chichester, England) |
| 15869278 | 2005-05-11 | Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo species | Journal of the American Chemical Society |
| 14664585 | 2003-12-17 | Axial chirality in 1,4-disubstituted (ZZ)-1,3-dienes. Surprisingly low energies of activation for the enantiomerization in synthetically useful fluxional molecules | Journal of the American Chemical Society |
