2,2,2-Trifluoroethyl methacrylate
Product Information
Molecular Formula
C6H7F3O2
Molecular Weight
168.11
Description
For reduced refractive index (1.437) polymers.
Synonyms
2,2,2-trifluoroethyl 2-methylprop-2-enoate
IUPAC Name
2,2,2-trifluoroethyl 2-methylprop-2-enoate
SMILES
CC(=C)C(=O)OCC(F)(F)F
InChI
InChI=1S/C6H7F3O2/c1-4(2)5(10)11-3-6(7,8)9/h1,3H2,2H3
InChI Key
QTKPMCIBUROOGY-UHFFFAOYSA-N
Boiling Point
59 °C (100 mmHg)
Flash Point
25 °C
Purity
95 %
Density
1.181 g/cm3
Appearance
Clear colorless liquid
Application
TFEMA can be used in the preparation of poly(TFEMA), which can be used in the development of acrylic protective coatings.
Storage
Keep Cold
Refractive Index
n20/D 1.361
Stability
May undergo autopolymerization.
LogP
1.66800
Safety Information
Hazards
H226:
Flammable liquid and vapour.
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
Flammable liquid and vapour.
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
Precautionary Statement
P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P310, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501
Signal Word
Danger
Computed Properties
XLogP3
2.7
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
5
Rotatable Bond Count
3
Exact Mass
168.03981395 g/mol
Monoisotopic Mass
168.03981395 g/mol
Topological Polar Surface Area
26.3Ų
Heavy Atom Count
11
Formal Charge
0
Complexity
171
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114185246-A | High-precision photoresist composition and direct writing system thereof | 2022-02-17 |
| CN-114133783-A | Polymer putty, putty coating, preparation method, putty coating and application | 2021-12-30 |
| CN-114181366-A | Modified acrylic polyol composition | 2021-12-30 |
| CN-114181340-A | Modified styrene-maleic anhydride resin and preparation method and application thereof | 2021-12-24 |
| CN-114085558-A | Staged photocuring coating, heat transfer film, decorative device and preparation method | 2021-12-22 |
| CN-114133532-A | Fluorine-containing polyacrylate modified polyurethane elastomer and preparation method thereof | 2021-12-16 |
| CN-114149548-A | Flame-retardant acrylic resin and solvent-type thermal foaming inkjet ink prepared from same | 2021-12-15 |
| CN-113980194-A | Organic silicon modified hydroxyl epoxy acrylic resin, UV ink and preparation method thereof | 2021-12-13 |
| CN-113999574-A | Fluorine-containing anticorrosive material and preparation method thereof | 2021-12-09 |
| CN-113999354-A | Amphiphilic block polymer nanoparticles with different morphologies and preparation method and application thereof | 2021-12-07 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22551478 | 2012-07-15 | Hierarchical dual-sized film surface morphologies self-generated from fluorinated binary latex blends boost hydrophobicity and lipophobicity | Journal of colloid and interface science |
| 22204970 | 2012-03-01 | Synthesis and self-assembly of amphiphilic gradient copolymer via RAFT emulsifier-free emulsion polymerization | Journal of colloid and interface science |
| 20825194 | 2010-10-05 | Modification of surface wettability through adsorption of partly fluorinated statistical and block polyelectrolytes from aqueous medium | Langmuir : the ACS journal of surfaces and colloids |
| 20827030 | 2010-10-01 | Kinetic polymerization behavior of fluorinated monomers for dental use | Dental materials journal |
| 20121228 | 2010-02-23 | Direct patterning of intrinsically electron beam sensitive polymer brushes | ACS nano |
| 19822997 | 2009-09-01 | Bonding durability against water of a fluorine-containing resin for precious metal alloys | Dental materials journal |
| 20355827 | 2009-09-01 | Development of a directly patterned low-surface-energy polymer brush in supercritical carbon dioxide | ACS applied materials & interfaces |
| 20356016 | 2009-04-01 | Copolymer-based progressive addition lens with graded index designed for astigmatism and distortion correction | ACS applied materials & interfaces |
| 19156765 | 2009-02-01 | CEC with new monolithic stationary phase based on a fluorinated monomer, trifluoroethyl methacrylate | Electrophoresis |
| 19009087 | 2008-11-30 | Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide: preparation of scCO2 soluble polymers with low catalytic residues | Chemical communications (Cambridge, England) |
