4,4'-Biphenyldicarboxylic acid
Product Information
Molecular Formula
C14H10O4
Molecular Weight
242.23
Description
Dendrimer building block.
Synonyms
4-(4-carboxyphenyl)benzoic acid; 4-(4-carboxyphenyl)benzoic acid
IUPAC Name
4-(4-carboxyphenyl)benzoic acid
SMILES
C1=CC(=CC=C1C2=CC=C(C=C2)C(=O)O)C(=O)O
InChI
InChI=1S/C14H10O4/c15-13(16)11-5-1-9(2-6-11)10-3-7-12(8-4-10)14(17)18/h1-8H,(H,15,16)(H,17,18)
InChI Key
NEQFBGHQPUXOFH-UHFFFAOYSA-N
Boiling Point
482.5±38.0 °C (Predicted)
Melting Point
283 °C (dec.)
Purity
> 97.0 % (T)
Density
1.347±0.06 g/cm3(Predicted)
Appearance
White to light yellow to light orange powder to crystaline
Application
Used as an intermediate.
LogP
2.75000
Safety Information
Hazards
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
Causes skin irritation.
H319:
Causes serious eye irritation.
Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
3.4
Hydrogen Bond Donor Count
2
Hydrogen Bond Acceptor Count
4
Rotatable Bond Count
3
Exact Mass
242.05790880 g/mol
Monoisotopic Mass
242.05790880 g/mol
Topological Polar Surface Area
74.6Ų
Heavy Atom Count
18
Formal Charge
0
Complexity
278
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114106825-A | Sulfur-phosphorus co-doped carbon point @ Zr-MOFs based on sesame straw and preparation method and application thereof | 2021-12-17 |
| CN-114085385-A | Preparation method of modified metal organic framework for removing impurities in hydrogen storage material | 2021-12-02 |
| CN-114086189-A | Environment-friendly stainless steel pickling passivation solution | 2021-11-24 |
| CN-114163641-A | Ammonium polybenzimidazole and alkaline ion exchange membrane thereof, and preparation method and application of ionomer | 2021-11-12 |
| CN-113861962-A | Ratiometric fluorescent probe, preparation method thereof and application thereof in detection of hydrogen peroxide | 2021-11-01 |
| CN-113683532-A | Preparation method of citronellonitrile and catalyst adopted by same | 2021-10-27 |
| CN-113683532-B | Preparation method of citronellonitrile and catalyst adopted by same | 2021-10-27 |
| CN-113817158-A | Preparation method of high-temperature-resistant nylon resin | 2021-10-26 |
| CN-113896901-A | Lead halide-based metal organic framework material, preparation and application thereof, ammonia gas sensor and intelligent sensing device | 2021-10-25 |
| CN-114044913-A | Metal-organic framework material and preparation method thereof | 2021-10-25 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22946624 | 2012-09-17 | Tuning structural topologies of three photoluminescent metal-organic frameworks via isomeric biphenyldicarboxylates | Inorganic chemistry |
| 22899097 | 2012-09-05 | Molecular self-assembly on an insulating surface: interplay between substrate templating and intermolecular interactions | Journal of physics. Condensed matter : an Institute of Physics journal |
| 22524410 | 2012-05-07 | Triple framework interpenetration and immobilization of open metal sites within a microporous mixed metal-organic framework for highly selective gas adsorption | Inorganic chemistry |
| 22228032 | 2012-04-14 | Entangled coordination polymers with mixed N- and O-donor organic linkers: a case of module-matching priority | Dalton transactions (Cambridge, England : 2003) |
| 22187720 | 2012-02-07 | H2 storage in isostructural UiO-67 and UiO-66 MOFs | Physical chemistry chemical physics : PCCP |
| 22220923 | 2012-02-06 | Series of metal organic frameworks assembled from Ln(III), Na(I), and chiral flexible-achiral rigid dicarboxylates exhibiting tunable UV-vis-IR light emission | Inorganic chemistry |
| 21973224 | 2011-12-06 | Effect of time, temperature, and kinetics on the hysteretic adsorption-desorption of H2, Ar, and N2 in the metal-organic framework Zn2(bpdc)2(bpee) | Langmuir : the ACS journal of surfaces and colloids |
| 21974551 | 2011-09-28 | A low energy electron microscopy study of the initial growth, structure, and thermal stability of 4,4'-biphenyldicarboxylic acid domains on Cu(001) | The Journal of chemical physics |
| 21736366 | 2011-08-17 | Understanding the preferential adsorption of CO2 over N2 in a flexible metal-organic framework | Journal of the American Chemical Society |
| 21547962 | 2011-06-06 | Modulated synthesis of Zr-based metal-organic frameworks: from nano to single crystals | Chemistry (Weinheim an der Bergstrasse, Germany) |
