2-(2-Bromoisobutyryloxy)ethyl methacrylate
Product Information
Molecular Formula
C10H15BrO4
Molecular Weight
279.13
Description
Atom Transfer Radical Polymerization (ATRP) initiator with a methacrylate functionality for branched polymerization, orthogonal polymerization, or other functionalization.
Synonyms
2-Methacryloxyethyl 2'-bromoisobutyrate,2-Methylacrylic acid 2-(2-bromo-2-methylpropionyloxy) ethyl ester,BIEM
IUPAC Name
2-(2-methylprop-2-enoyloxy)ethyl 2-bromo-2-methylpropanoate
SMILES
CC(=C)C(=O)OCCOC(=O)C(C)(C)Br
InChI
InChI=1S/C10H15BrO4/c1-7(2)8(12)14-5-6-15-9(13)10(3,4)11/h1,5-6H2,2-4H3
InChI Key
QXDYJUSFCUKOQD-UHFFFAOYSA-N
Boiling Point
162-164 °C(lit.)
Flash Point
>230 °F
Purity
95%
Density
1.303 g/mL at 25 °C
Appearance
powder
Storage
2-8°C
Refractive Index
n20/D 1.471
Safety Information
Hazards
H302
Computed Properties
XLogP3
2.4
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
4
Rotatable Bond Count
7
Exact Mass
278.01537 g/mol
Monoisotopic Mass
278.01537 g/mol
Topological Polar Surface Area
52.6Ų
Heavy Atom Count
15
Formal Charge
0
Complexity
271
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-113667066-A | Brush-like microgel water lubricating additive and preparation method and application thereof | 2021-09-17 |
| CN-112871147-A | Preparation method of chromatography medium for removing polymers in monoclonal antibody | 2020-12-30 |
| JP-2022041530-A | Method for manufacturing grafted fine particles | 2020-09-01 |
| EP-3916029-A1 | Novel methacrylate copolymer and compositions comprising it | 2020-05-28 |
| WO-2021239787-A1 | Novel methacrylate copolymer and compositions comprising it | 2020-05-28 |
| WO-2021199748-A1 | Composition, film, and optical sensor | 2020-03-30 |
| TW-202136364-A | Composition, film and light sensor | 2020-03-30 |
| WO-2021180943-A1 | Compositions improving poxvirus stability | 2020-03-12 |
| JP-2021123712-A | Compositions, hardened films, laminates, ships, underwater structures, medical devices, and microchannel chips | 2020-01-31 |
| AU-2020397432-A1 | Hydrogel | 2019-12-02 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 21028818 | 2010-12-07 | Pickering emulsion templated interfacial atom transfer radical polymerization for microencapsulation | Langmuir : the ACS journal of surfaces and colloids |
| 15144819 | 2004-06-15 | Architecture and solution properties of AB-type brush-block-brush amphiphilic copolymers via ATRP techniques | Journal of colloid and interface science |
