4,4'-Di-tert-butyl-2,2'-dipyridyl
| Catalog Number | Size | Price | Stock | Quantity |
|---|---|---|---|---|
| BPM-326382 | 100 g | $1199 | In stock |
Product Information
Molecular Formula
C18H24N2
Molecular Weight
268.40
Description
2,2'-Bipyridyl has been used in the preparation of copper(II)-bipyridine-naringenin complex. It may be used in the preparation of 2,2'-bipyridyl hydrobromide.
Synonyms
4,4'-Di-tert-butyl-2,2'-bipyridine; 4-tert-Butyl-2-(4-tert-butyl-2-pyridyl)pyridine; 2,2'-Bipyridine, 4,4'-bis(1,1-dimethylethyl)-; 4,4'-Bis(di-t-butyl)-2,2'-bipyridine
IUPAC Name
4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine
SMILES
CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C
InChI
InChI=1S/C18H24N2/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6/h7-12H,1-6H3
InChI Key
TXNLQUKVUJITMX-UHFFFAOYSA-N
Boiling Point
395.4±42.0 °C (Predicted)
Melting Point
159-161 °C (lit.)
Flash Point
228.2 °F
Purity
98%
Density
0.977 g/cm3
Solubility
Soluble in DMSO (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
Appearance
White to Off-white Solid
Storage
Store at RT
Refractive Index
n20/D 1.519
LogP
4.73860
Safety Information
Hazards
H315 H319
Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
4.8
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
3
Exact Mass
268.193948774 g/mol
Monoisotopic Mass
268.193948774 g/mol
Topological Polar Surface Area
25.8Ų
Heavy Atom Count
20
Formal Charge
0
Complexity
278
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114032567-A | Electrochemical reduction carboxylation method based on non-sacrificial anode strategy | 2021-11-23 |
| CN-114031644-A | Neutral iridium complex containing nitrogen-sulfur four-membered ring coordination, and preparation method and application thereof | 2021-11-22 |
| CN-113801033-A | Synthesis method of 2-aminoindan or derivatives thereof | 2021-11-16 |
| CN-113801033-B | Synthesis method of 2-aminoindan or derivatives thereof | 2021-11-16 |
| CN-113999083-A | Novel method for synthesizing 2, 2-difluoroethyl aromatic compound | 2021-10-18 |
| CN-113896648-A | Preparation method of alpha, beta-unsaturated amide compound | 2021-09-29 |
| CN-113683646-A | Monocarbon borane-containing metal platinum complex and preparation method and application thereof | 2021-09-18 |
| CN-113621131-A | Polyelectrolyte material, preparation method thereof and polyelectrolyte membrane | 2021-09-15 |
| CN-113582843-A | Preparation method of 5-chloro-2-fluoro-3-hydroxybenzoic acid ethyl ester | 2021-09-09 |
| CN-113698416-A | Singlet oxygen carrier for inhibiting beta-amyloid protein aggregation and preparation method and application thereof | 2021-08-25 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22684499 | 2012-07-21 | Tailoring carrier injection efficiency to improve the carrier balance of solid-state light-emitting electrochemical cells | Physical chemistry chemical physics : PCCP |
| 22731752 | 2012-07-06 | Iridium-catalyzed, substrate-directed C-H borylation reactions of benzylic amines | Organic letters |
| 22676275 | 2012-06-18 | Scrutinizing low-spin Cr(II) complexes | Inorganic chemistry |
| 22591116 | 2012-06-04 | Large improvement in the catalytic activity due to small changes in the diimine ligands: new mechanistic insight into the dirhodium(II,II) complex-based photocatalytic H2 production | Inorganic chemistry |
| 22415854 | 2012-04-16 | Synthesis of 2- and 2,7-functionalized pyrene derivatives: an application of selective C-H borylation | Chemistry (Weinheim an der Bergstrasse, Germany) |
| 22372402 | 2012-03-19 | An octanuclear molybdenum(VI) complex containing coordinatively bound 4,4'-di-tert-butyl-2,2'-bipyridine, [Mo8O22(OH)4(di-tBu-bipy)4]: synthesis, structure, and catalytic epoxidation of bio-derived olefins | Inorganic chemistry |
| 22258081 | 2012-03-07 | Photophysical properties of 4,4'-di-tert-butyl-2,2'-bipyridine supported 6-membered 2,2'-diphenyl-X platinacycles (X = CH2, NMe, O) | Dalton transactions (Cambridge, England : 2003) |
| 22045119 | 2012-01-21 | A systematic study on the synthesis, reactivity and structure of ortho-palladated aryloximes, including the first cyclopalladated aryloximato and iminoaryloxime complexes | Dalton transactions (Cambridge, England : 2003) |
| 22066656 | 2011-12-05 | Thiocyanate linkage isomerism in a ruthenium polypyridyl complex | Inorganic chemistry |
| 22199539 | 2011-12-01 | μ-Oxido-bis-[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-κN,N')dioxido-molybdenum(VI)] 0.2-hydrate | Acta crystallographica. Section E, Structure reports online |
