Bis(triphenylphosphine)nickel(II)chloride
| Catalog Number | Size | Price | Stock | Quantity |
|---|---|---|---|---|
| BPM-364903 | 1 kg | $499 | In stock |
Product Information
Molecular Formula
C36H30Cl2NiP2
Molecular Weight
654.17
Description
Bis(triphenylphosphine)nickel(II)chloride is used as a coordination compound for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.
Synonyms
Nickel, dichlorobis(triphenylphosphine)-; Bis(tri-N-butylphosphine)dichloronickel; Dichlorobis(triphenyIphosphine)-nickel(II)
IUPAC Name
dichloronickel;bis(triphenylphosphane)
SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ni]Cl
InChI
InChI=1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChI Key
ZBRJXVVKPBZPAN-UHFFFAOYSA-L
Melting Point
250 °C (dec.)(lit.)
Flash Point
Not applicable
Purity
98%
Solubility
Soluble in DMSO (Slightly), Methanol (Slightly)
Appearance
Dark Green to Dark Gray Crystals
Application
Ni(PPh3)2Cl2 may be used to undertake nickel assisted phosphination of biaryl O,N triflates with chlorodiphenylphosphine.
Storage
Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.
LogP
4.04770
Safety Information
Hazards
H302 H372 H317 H334 H350
Precautionary Statement
P501 P272 P260 P270 P202 P201 P264 P280 P284 P302 + P352 P308 + P313 P362+P364 P304 + P340 P333 + P313 P301 + P312 + P330 P405
Signal Word
Danger
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
6
Exact Mass
652.055322 g/mol
Monoisotopic Mass
652.055322 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
41
Formal Charge
0
Complexity
204
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
3
Compound Is Canonicalized
Yes
