tert-Butyl methacrylate
Product Information
Molecular Formula
C8H14O2
Molecular Weight
142.20
Description
tert-Butyl methacrylate (CAS# 585-07-9) is a useful research chemical.
Synonyms
tert-butyl 2-methylprop-2-enoate
IUPAC Name
tert-butyl 2-methylprop-2-enoate
SMILES
CC(=C)C(=O)OC(C)(C)C
InChI
InChI=1S/C8H14O2/c1-6(2)7(9)10-8(3,4)5/h1H2,2-5H3
InChI Key
SJMYWORNLPSJQO-UHFFFAOYSA-N
Boiling Point
132 °C
Melting Point
-60 °C
Flash Point
30 °C
Purity
95 %
Density
0.875 g/cm3
Solubility
water, 555.3 mg/L @ 25 °C (est)
Appearance
A colorless liquid with an ester like odor. flash point below 141°f. less dense than water and insoluble in water.
Application
tert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, biomaterials and flocculants.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Refractive Index
n20/D 1.415(lit.)
LogP
1.90420
Safety Information
Hazards
H226:
Flammable liquid and vapour.
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
H335:
May cause respiratory irritation.
Flammable liquid and vapour.
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
H335:
May cause respiratory irritation.
Precautionary Statement
P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
2.5
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
3
Exact Mass
142.099379685 g/mol
Monoisotopic Mass
142.099379685 g/mol
Topological Polar Surface Area
26.3Ų
Heavy Atom Count
10
Formal Charge
0
Complexity
151
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| JP-2022033265-A | Adhesive sheets, repetitive bending laminated members and repetitive bending devices | 2022-01-04 |
| CN-114085311-A | Method for preparing high-purity photoresist resin | 2021-12-30 |
| CN-114085559-A | Antifogging and antifrosting film and preparation method thereof | 2021-12-30 |
| CN-114058199-A | UV-cured super-hydrophilic anti-fog coating and preparation method and application thereof | 2021-12-29 |
| JP-2022034050-A | toner | 2021-12-27 |
| CN-114149750-A | Adhesive, heat-curable adhesive tape, and preparation method and use method thereof | 2021-12-14 |
| CN-113917577-A | High-water-resistance and bending-resistance optical protective film, polarizer and liquid crystal display device | 2021-12-13 |
| CN-114149527-A | Method for realizing controllable free radical polymerization in air atmosphere and application thereof | 2021-12-10 |
| CN-114163569-A | Water-resistant surface sizing agent and preparation method and application thereof | 2021-12-10 |
| CN-114085485-A | Preparation of modified collagen fiber and application thereof in rubber | 2021-12-08 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22384926 | 2012-03-20 | Dye-loaded porous nanocapsules immobilized in a permeable polyvinyl alcohol matrix: a versatile optical sensor platform | Analytical chemistry |
| 22755055 | 2012-03-01 | Thermal-sensitive PBMA-b-PNIPAAm amphiphilic block copolymers brushes and their assembling micelles | Journal of nanoscience and nanotechnology |
| 22112235 | 2012-01-10 | Formation of polyampholyte brushes via controlled radical polymerization and their assembly in solution | Langmuir : the ACS journal of surfaces and colloids |
| 22489207 | 2012-01-01 | Separation of poly(styrene-block-t-butyl methacrylate) copolymers by various liquid chromatography techniques | TheScientificWorldJournal |
| 21919469 | 2011-11-01 | Temperature- and pH-triggered reversible transfer of doubly responsive hairy particles between water and a hydrophobic ionic liquid | Langmuir : the ACS journal of surfaces and colloids |
| 21919505 | 2011-10-01 | Scanning thermal lithography of tailored tert-butyl ester protected carboxylic acid functionalized (meth)acrylate polymer platforms | ACS applied materials & interfaces |
| 22110867 | 2011-01-01 | Anisotropic nanomaterials: structure, growth, assembly, and functions | Nano reviews |
| 20232838 | 2010-06-15 | Self-assembly of poly(4-methylstyrene)-g-poly(methacrylic acid) graft copolymer in selective solvents for grafts: scattering and molecular dynamics simulation study | Langmuir : the ACS journal of surfaces and colloids |
| 20099880 | 2010-06-01 | Thermosensitive aqueous gels with tunable sol-gel transition temperatures from thermo- and pH-responsive hydrophilic ABA triblock copolymer | Langmuir : the ACS journal of surfaces and colloids |
| 19754064 | 2010-01-19 | Amphoteric core-shell microgels: contraphilic two-compartment colloidal particles | Langmuir : the ACS journal of surfaces and colloids |
